MATHESON TRI-GAS, INC. -- SODIUM METAL -- -
===================== Product Identification ===================== Product ID:SODIUM METAL MSDS Date:Jan 24 1989 Kit Part:=== Responsible Party === Company Name:MATHESON TRI-GAS, INC. Address:959 ROUTE 46 EAST City:PARSIPPANY State:NJ ZIP:07054-0624 Country:US Info Phone Num:(USA) 973-257-1100, (WHITBY) 905-668-3570, (EDMONTON) 780-471-4036 Chemtrec Ind/Phone:18004249300 === Contractor Identification === Company Name:MATHESON TRI-GAS, INC. Address:959 ROUTE 46 EAST Box:City:PARSIPPANY State:NJ ZIP:07054-0624 Country:US Phone:(USA) 973-257-1100, (WHITBY) 905-668-3570, (EDMONTON) 780-471-4036 CAGE:Company Name:MATHESON TRI-GAS, INC. Address:530 WATSON STREET Box:City:WHITBY State:ZIP:L1N 5R9 Country:ONTARIO, CANADA Phone:(USA) 973-257-1100, (WHITBY) 905-668-3570, (EDMONTON) 780-471-4036 CAGE: ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM METAL CAS:7440-23-5 Fraction by Wt: 100% ===================== Hazards Identification ===================== Reports of Carcinogenicity:NTP:No IARC:No OSHA:No Medical Cond Aggravated by Exposure: ======================= First Aid Measures ======================= First Aid: INHALATION: If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. If breathing is difficult, oxygen should be administered by qualified personnel. Get immediate medical attention. SKIN CONTACT: Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get immediate medical attention. Thoroughly clean and dry contaminated clothing and shoes before reuse. Destroy contaminated shoes. EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention. INGESTION: DO NOT induce vomiting. Never make an unconscious person vomit or drink fluids. Give large amounts of water or milk. When vomiting occurs, keep head lower than hips to help prevent aspiration. If person is unconscious, turn head to side. Get medical attention immediately. NOTE TO PHYSICIAN: For inhalation, consider oxygen. For ingestion, consider esophagoscopy. Avoid gastric lavage. ===================== Fire Fighting Measures ===================== Flash Point:flammable Autoignition Temp:250 F (121 C) Extinguishing Media:regular dry chemical, dry sand, lime, soda ash Large fires: Flood with water. Apply water from a protected location or from a safe distance. Fire Fighting Procedures:Do not use water. Do not use foam. Move container from fire area if it can be done without risk. Unusual Fire/Explosion Hazard:Severe fire hazard. ================== Accidental Release Measures ================== Neutralizing Agent: ====================== Handling and Storage ====================== Handling and Storage Precautions:Protect from physical damage. Keep out of water supplies and sewers. Store at room temperature. Store under an inert atmosphere. Store under an oxygen-free liquid (e.g., certain petroleum oils). Keep separated from incompatible substances. Store outside or in a detached building. Other Precautions: ============= Exposure Controls/Personal Protection ============= Respiratory Protection:Under conditions of frequent use or heavy exposure, respiratory protection may be needed. Respiratory protection is ranked in order from minimum to maximum. Consider warning properties before use. Any dust, mist, and fume respirator. Any air-purifying respirator with a high-efficiency particulate filter. Any powered, air-purifying respirator with a dust, mist, and fume filter. Any powered, air-purifying respirator with a high-efficiency particulate filter. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with full facepiece and operated in a pressure-demand or other positive-pressure mode in combination with a separate escape supply. Any self-contained breathing apparatus with a full facepiece. Ventilation:Provide local exhaust ventilation system. Ventilation equipment should be explosion-resistant if explosive concentrations of material are present. Ensure compliance with applicable exposure limits. Protective Gloves:Wear appropriate chemical resistant gloves. Eye Protection:Wear splash resistant safety goggles with a faceshield. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. Other Protective Equipment:Wear appropriate chemical resistant clothing. Supplemental Safety and Health SODIUM METAL: No occupational exposure limits established. ================== Physical/Chemical Properties ================== Boiling Pt:1621 F (883 C) Vapor Pres:1.23 mmHg @ 400 C Vapor Density:Not applicable Spec Gravity:0.9684 @ 20 C pH:basic in solution Evaporation Rate & Reference:Not applicable Solubility in Water:reacts violently Appearance and Odor:PHYSICAL STATE:solid COLOR:gray ODOR:odorless Corrosion Rate: ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:May ignite on exposure to air. Polymerizes with evolution of heat. Avoid contact with light. Stability Condition to Avoid:Avoid contact with air. Keep dry. Keep out of water supplies and sewers. Hazardous Decomposition Products:Thermal decomposition products: oxides of sodium Thermal decomposition products: oxides of sodium Conditions to Avoid Polymerization:Will not polymerize. =================== Toxicological Information =================== Toxicological Information:SODIUM METAL: LOCAL EFFECTS: Corrosive: inhalation, skin, eye, ingestion ACUTE TOXICITY LEVEL: Insufficient Data. ===================== Ecological Information ===================== Ecological:ECOTOXICITY DATA: FISH TOXICITY: 5000000 ug/L 24 day(s) LETH (Mortality) Ayu (Plecoglossus altivelis) INVERTEBRATE TOXICITY: 1640000 ug/L 48 hour(s) EC50 (Immobilization) Water flea (Daphnia magna) ALGAL TOXICITY: 230000 ug/L 1 week(s) (Enzyme) Flagellate euglenoid (Euglena gracilis) ==================== Disposal Considerations ==================== Waste Disposal Methods:Dispose in accordance with all applicable regulations. =================== MSDS Transport Information =================== Transport Information:U.S. DOT 49 CFR 172.101: PROPER SHIPPING NAME: Sodium ID NUMBER: UN1428 HAZARD CLASS OR DIVISION: 4.3 PACKING GROUP: I LABELING REQUIREMENTS: Dangerous when wet QUANTITY LIMITATIONS: PASSENGER AIRCRAFT OR RAILCAR: Forbidden CARGO AIRCRAFT ONLY: 15 kg ===================== Regulatory Information ===================== SARA Title III Information: SARA TITLE III SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355.30): Not regulated. SARA TITLE III SECTION 304 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355.40): Not regulated. SARA TITLE III SARA SECTIONS 311/312 HAZARDOUS CATEGORIES (40 CFR 370.21): ACUTE: Yes CHRONIC: No FIRE: Yes REACTIVE: Yes SUDDEN RELEASE: Yes SARA TITLE III SECTION 313 (40 CFR 372.65): Not regulated. Federal Regulatory Information:CERCLA SECTIONS 102a/103 HAZARDOUS SUBSTANCES (40 CFR 302.4): SODIUM METAL: 10LBSRQ OSHA PROCESS SAFETY (29CFR1910.119): Not regulated. State Regulatory Information: California Proposition 65: Not regulated. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.