CORNBELT CHEMICAL CO -- WEEDPRO 4 LB AMINE -- 6840-01-261-6910
===================== Product Identification ===================== Product ID:WEEDPRO 4 LB AMINE MSDS Date:01/30/1995 FSC:6840 NIIN:01-261-6910 === Responsible Party === Company Name:CORNBELT CHEMICAL CO Box:410 City:MCCOOK State:NE ZIP:69001 Info Phone Num:800-652-9306, 800-424-9300 Emergency Phone Num:800-652-9306, 800-424-9300 CAGE:0AGD9 === Contractor Identification === Company Name:CORNBELT CHEMICAL COMPANY Address:1515 MOCKINGBIRD AVENUE Box:City:MCCOOK State:NE ZIP:69001 Phone:(800) 652-9306 CAGE:0AGD9 ============= Composition/Information on Ingredients ============= Ingred Name:2,4-D ACID, DIMETHYLAMINE SALT CAS:2008-39-1 Fraction by Wt: 46.6% Other REC Limits:NONE RECOMMENDED OSHA PEL:10 MG/M3 FREE ACID ACGIH TLV:10 MG/M3 FREE ACID Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Other REC Limits:NONE RECOMMENDED Ingred Name:DIMETHYLAMINE (CERCLA) CAS:124-40-3 RTECS #:IP8750000 Other REC Limits:NONE RECOMMENDED EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:INERT INGREDIENTS Other REC Limits:NONE RECOMMENDED OSHA PEL:NOT RELEVANT ACGIH TLV:NOT RELEVANT ===================== Hazards Identification ===================== LD50 LC50 Mixture:* Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:INHALATION: VAPOR/SPRAY MISTS MAY IRRITATE RESP TRACT, CAUSE NAUSEA/MYOTONIA/MUSCLE WEAKNESS/FALLING BP. EYE: SEVERE IRRIT. CAUSES IRREVERSIBLE EYE DAMAGE SEEN AS CORNEAL OPACITY. VAPORS/SPRAY MISTS I RRIT EYES. MAY CAUSE PERMANENT IMPAIRMENT/BLINDNESS. SKIN: MINIMAL IRRIT. MAY BE HARMFUL IF ABSORBED. INGEST: HARMFUL** Explanation of Carcinogenicity:PHENOXYACETIC ACID HERBICIDES LISTED AS CLASS 2B CARCINOGEN LIMITED EVIDENCE OF CARCINOGENICITY IN HUMANS. Effects of Overexposure:**MAY CAUSE GI IRRIT/ULCERATION. AMTS INGESTED INCIDENTAL TO INDUSTRIAL HANDLING/NOT LIKELY TO INJURE. ======================= First Aid Measures ======================= First Aid:INHALATION: GET FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL RESP. GIVE OXYGEN IF NEEDED. GET MED AID. EYE: HOLD LIDS OPEN. WASH W/STEADY GENTLE STREAM WATER >15 MIN. GET MED AID (OPHTHALMOLOGIST). SKI N: IMMED WASH W/LOTS SOAP & WATER. REMOVE CONTAM CLOTHES/SHOES/WASH BEFORE REUSE. IF IRRIT PERSISTS GET MED AID. INHAL: IF CONSCIOUS GIVE 2-3 GLASSES WATER/MILK. DON'T INDUCE VOMITING. GET MED AID. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:190F,88C Lower Limits:NA Upper Limits:NA Extinguishing Media:ALCOHOL FOAM, CO2, DRY CHEMICAL. Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND SCBA. DIKE TO PREVENT RUNOFF AND CONTAMINATION OF WATER SOURCES. ================== Accidental Release Measures ================== Spill Release Procedures:DIKE LARGE SPILLS. ABSORB SMALL SPILLS ON INERT MATERIAL (SAND/VERMICULITE). WEAR APPROP PROTECTIVE EQUIP. DON'T CONTAMINATE PUBLIC WATER SOURCES. ====================== Handling and Storage ====================== Handling and Storage Precautions:AVOID INGESTION OR INHALATION. DON'T GET IN EYES, ON SKIN OR CLOTHING. DON'T CONTAMINATE WATER/FOOD/FEED BY STORAGE OR DISPOSAL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR FOR PESTICIDE MIST. *ORAL LD50 1150 MG/KG; DERMAL LD50 MALE RABBIT 1122 MG/M3 FEMALE RABBIT 909 MG/KG. Ventilation:LOCAL EXHAUST PREFERRABLE. Protective Gloves:IMPERVIOUS Eye Protection:FACE SHIELD, GOGGLES Other Protective Equipment:EYEBATH. FULL BODY PROTECTIVE CLOTHING, SAFETY SHOWER. Supplemental Safety and Health NK ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>212F,>100C Melt/Freeze Pt:M.P/F.P Text:-6F,-21C Vapor Pres:25C Vapor Density:NA Spec Gravity:1.16 @ 22C pH:7.5-10 Solubility in Water:100% @ 25C Appearance and Odor:CLEAR, BROWN TO BLACK LIQUID, CHARACTERISTIC PHENOXY ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING AGENTS, ACIDS. Stability Condition to Avoid:EXCESSIVE HEAT Hazardous Decomposition Products:HYDROGEN CHLORIDE, NITROGEN OXIDES MAY BE PRODUCED ON DECOMPOSITION. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN AN APPROVED LANDFILL OR INCINERATOR FOLLOWING ALL APPLICABLE FEDERAL, STATE, LOCAL REGS. TRIPPLE RINSE ALL CONTAINERS. PUNCTURE/CRUSH/OFFER FOR RECYCLING/RECONDITIONING IF POSSIBLE. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.